Did you try cleaning the Zorro slots and reseating the Buster?
I cleaned the Zorros thoroughly last month, and replaced my Buster 9 with a new 11 from Amigakit a few weeks ago. Everything else on the system seems to be working flawlessly, the X-Surf, Picasso IV, Bigram +
I've had some suggestions that it could be a PSU issue as the A4000 PSU might be pushed to its limit with an RTG Card, RAM and the X-Surf.
I don't have the Rapidroad connected to the floppy power though, is that mandatory? The included instructions suggested it was just optional for high powered USB devices. I have ordered a molex to floppy adapter so I can plug it in though.